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Beilstein J. Org. Chem. 2007, 3, No. 2, doi:10.1186/1860-5397-3-2
Graphical Abstract
Scheme 1: Ultrasound-assisted photocatalytic ring opening of α-epoxyketones.
Scheme 2: Possible intermediates involved in the ring opening of α-epoxyketones.
Scheme 3: Possible formation of a complex involved in reaction in acetone.
Scheme 4: Interaction of oxygen lone pair of carbonyl group with carbocation center.
Figure 1: The semi-empirical PM3 calculations for interaction of 1a with NBTPT.